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Menschen Seit Singvogel bestimmung online dating Stunden gibt es den modernen Menschen. Petrographic and geochemical data of this portion showed limestones and dolostones with high terrigenous content and low Sr concentrations. On the other hand, carbonates from upper Sete Lagoas Formation were subjected to extensive geochemical and Sr isotopic analysis due to their low terrigenous content and degree of post-depositional alteration. However, some carbonates are usually susceptible to post-depositional alterations, especially those of Precambrian age, which change the original isotopic and geochemical seawater record.
Recognition of post-depositional alteration processes is extremely important to ensure the reliable application of C isotopic chemostratigraphy Melezhik et al. Therefore, several authors present many post-depositional alteration geochemical parameters Asmeron et al.
In all cases, such geochemical parameters and their threshold values are empirical. These parameters were chosen as they consider different reliability limits for C and Sr isotope and are more rigorous than the others. The C and O isotope compositions of these carbonates are very fluctuating and display a negative correlation between them Fig. This correlation can be the result of fluid-rock interactions when fluids with a different oxygen isotopic composition infiltrate a sediment i.
Field and petrographic data support the interpretation of dolomitization as the major post-depositional processes affecting these carbonates due to significant occurrences of impure recrystallized dolostones and some limestones, deformed micaceous shales and interlayered clays and oxides, usually associated with tectonic structures, such as local thrust folds and faults, calcite veins and mineral recrystallization.
Cap carbonate data from Vieira et al. Key for different sections is given in Fig. These values are interpreted as representative of the depositional environment and can be correlated with those obtained by Santos et al. In addition, these carbon isotopic values are correlated with those obtained by KuchenbeckerAlvarenga et al. This may reflect a marine environment possibly in equilibrium with the contemporary global oceans.
The primary calcareous sedimentary structures, such as flat parallel lamination and low angle cross lamination indicate a deep marine environment, less affected by the influence of tidal currents or storms.
In this second stage of depositional environment evolution of the Sete Lagoas Formation, a second marine transgression with deeper water and less energy took place Vieira et al.
This carbon isotopic trend can be explained by various processes, such as increase of high burial rates of organic matter Knoll et al. Additionally, carbon isotopes are subject to seasonal variations due to their low residence time in the oceans, of around years Frimmel, As pointed out by Santos et al.
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On a regional scale, the same authors propose that high-C isotopic values are mainly due to 12C fixation through photosynthetic processes and great contribution of restricted basin, as this very positive C isotopic trend is characteristic of the upper Sete Lagoas Formation.
Inefficient circulation results in low oxygenation of deep waters, thus favoring preservation of organic matter, which leads to high rates of 13C in the water column.
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Additionally, positive C isotope excursions are observed in many episodes during Cryogenian and Ediacaran see Hebert et al. It is likely that during the dolomitization process, the primary Sr was leachate and radiogenic Sr from interstitial fluids has been incorporated into the chemical structure of carbonates.
However, disturbances of Sr isotope composition depend not only on the extent of post-depositional alteration but also on the initial composition of carbonates Melezhik et al. Carbonates from lower Sete Lagoas Formation present significant amounts of Si, Al and K, which indicate a contribution of detrital sediments and possibly influence of freshwater on the carbonate platform.
A decrease in such detrital input from East to West was noticed in the studied area, and therefore there was also decrease in the external waters input, which is corroborated by our geochemical data. According to Melezhik et al. These data suggest that the Sr isotope composition represents the depositional environment, and it is not affected by diagenesis or post-depositional processes.
Therefore, we suggest a specific assessment for each study section at the expenses of geochemical threshold values established in the literature. This suggests that carbonates of Sete Lagoas Formation probably have been deposited in a restricted epi-continental sea, like proposed by Paula-Santos et al. Additionally, large variations in the Sr isotope ratios are confined to the Eastern margin of the basin HV section.
Therefore, the isotope record of this sector was investigated in more details. Therefore, another explanation must be claimed. Sr concentrations, major elements and geochemical ratios of carbonates from Sete Lagoas section blue circles and Haras Veredas section red squares. Even so, Beck et al. While isotope exchange affects the isotopic seawater composition, it does not appear to modify the concentration of Rb, Sr, Si, Al, K and Fe elements Fig.
Therefore, a Sr isotopic local trend dominated by SGD, independent from detrital input, is suggested. In the modern ocean Sr budget, Beck et al. The direct flow of SGD into the ocean and the chemical reactions of meteoric and seawater mixtures within coastal aquifers are processes that have been largely ignored when estimating material flows between land and sea Moore, This discrepancy between distal and proximal environments dismisses any possibilities that the more radiogenic ratios in the HV section would represent connection periods to the global ocean; as such event should be recorded at regional scale.
The great homogeneity in the Sr isotope composition would indicate less influence of freshwater, suggesting that these limestones were deposited on the distal sector of the carbonate platform and preserve the original Sr isotope seawater composition.
Finally, the Sr ratios on the deep sectors devoid of freshwater influence are much lower than those predicted higher than 0. Carbonate dissolution calcite, dolomite and evaporitic sulfates gypsum, anhydrite are considered an important source of Sr to the ocean Brass, due to the high Sr content and solubility of those minerals. Dating Re entering the dating scene have made it easier to sift through the losers and avoid blind dates friends have set up.
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